We use a plugin called MagicSpells for all the active abilities at the moment. You can find out what you have to cast by typing /cast list. Also, you can do /help magicspells and /cast help for more information.
As far as usable exp, unfortunately the command is /money right now. i haven't figured out a good way to alias it to /exp. I use an economy plugin to simulate experience drops from mobs and you purchase your skills with it.
At some point there will be extensive documentation on all of this, but like I said before, I only just finished actually getting it all working. i haven't gotten that far yet